From Ferrous Sulfate to LFP: The Iron-Based Cathode Supply Chain Explained

Published October 22, 2026

From Ferrous Sulfate to LFP: The Iron-Based Cathode Supply Chain Explained

How LFP Batteries Are Made: The Complete Manufacturing Process

Lithium iron phosphate (LFP) has become the dominant chemistry in stationary energy storage and a fast-growing share of electric vehicles, valued for its safety, long cycle life, low cost, and freedom from nickel and cobalt. Most explanations of how LFP batteries are made stop at the process steps. This guide goes further: it walks through every stage of LFP cell manufacturing and names the specific chemical inputs behind each one, from the cathode precursor chemistry to the electrolyte formulation, because those materials are what actually determine cost, quality, and supply risk. It is written for the engineers and procurement teams who need to understand not just how a cell is built, but what goes into it.


The LFP manufacturing process at a glance

An LFP cell is built from four functional components, each made from distinct raw materials: a cathode (lithium iron phosphate on aluminum foil), an anode (graphite on copper foil), an electrolyte (a lithium salt dissolved in organic carbonate solvents), and a separator (a microporous polymer membrane). Manufacturing proceeds in roughly five phases: producing the active materials, mixing and coating electrode slurries, assembling the cell, filling it with electrolyte and sealing it, and finally forming and testing it. The sections below follow that sequence and identify the chemicals used at each step.


Stage 1: Making the cathode active material (LFP)

The cathode is what makes an LFP battery an LFP battery, and its production is a chemical supply chain in itself. The most widely used industrial route is the iron phosphate route, which runs in three steps.

First, ferrous sulfate (FeSO4), largely a by-product of titanium dioxide and steel production, is purified and then oxidized and precipitated with a phosphate source to form battery-grade ferric phosphate (FePO4·2H2O). Hydrogen peroxide is the common oxidant and phosphoric acid the phosphate source. Second, the ferric phosphate is blended with lithium carbonate and a carbon source such as glucose or sucrose. Third, that mixture is calcined at roughly 700–800 °C under an inert atmosphere, where the carbon reduces ferric iron to ferrous iron and leaves a conductive carbon coating on the particles, yielding lithium iron phosphate (LiFePO4).

The chemical inputs at this stage are therefore ferrous sulfate, ferric phosphate, and lithium carbonate, plus phosphoric acid and hydrogen peroxide. The purity of the ferric phosphate, particularly its iron-to-phosphate ratio, carries directly into the finished cathode's performance. We cover this chain in depth in our guide to the LFP cathode supply chain, and the reason LFP uses carbonate rather than hydroxide in our comparison of lithium carbonate vs lithium hydroxide.

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Stage 2: Making the cathode electrode

The finished LFP powder is turned into a usable electrode by mixing it into a slurry and coating it onto a metal foil. The cathode slurry combines three functional ingredients beyond the active material: a conductive carbon (carbon black) to carry electrons, a binder to hold the coating together, and a solvent to disperse everything into a workable paste.

For the cathode, the standard binder is polyvinylidene fluoride (PVDF), and the standard solvent is N-methyl-2-pyrrolidone (NMP). PVDF is chosen because it is electrochemically stable at the cathode's operating voltage and adheres the active material firmly to the foil; NMP is used because it dissolves PVDF cleanly and evaporates controllably during drying. The slurry is coated onto aluminum foil, which serves as the cathode current collector, then dried, during which the NMP is evaporated and recovered for reuse. The coated foil is then calendered (compressed between precision rollers) to the target density. The key non-active chemical inputs here are NMP as the slurry solvent and PVDF as the binder.


Stage 3: Making the anode electrode

The anode in an LFP cell is almost always graphite, which stores lithium ions during charging. It can be synthetic graphite, natural graphite, or a blend; synthetic graphite is favored where consistency and fast-charge performance matter. The graphite is mixed into a slurry with a conductive additive and a binder, then coated onto copper foil, which serves as the anode current collector, and dried and calendered in the same way as the cathode.

A notable difference from the cathode is the binder chemistry. The anode typically uses a water-based binder system of carboxymethyl cellulose (CMC) and styrene-butadiene rubber (SBR) rather than PVDF in NMP, which avoids the organic solvent on the anode side and lowers cost. The chemical inputs here are synthetic graphite as the active material plus the CMC/SBR binder system. A growing trend is the addition of small amounts of silicon to the graphite anode to raise energy density, though graphite remains the base material in virtually all LFP cells today.


Stage 4: Formulating the electrolyte

The electrolyte is the ion-conducting medium that moves lithium ions between the electrodes, and it is essentially a precisely formulated mixture of chemicals. It has three parts: a lithium salt, a blend of solvents, and a small dose of functional additives.

The standard lithium salt is lithium hexafluorophosphate (LiPF6), typically at around 1 molar concentration, chosen for its high ionic conductivity and good overall balance of properties. The salt is dissolved in a blend of organic carbonate solvents, because no single solvent does everything well. A cyclic carbonate, ethylene carbonate (EC), is essential for forming a stable protective layer on the anode and has high dielectric strength, but it is viscous and solid at room temperature. It is therefore blended with low-viscosity linear carbonates such as dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), and diethyl carbonate (DEC) to give the electrolyte good conductivity and a wide temperature range. A representative industrial formulation is 1M LiPF6 in an EC/EMC/DEC blend.

Finally, small amounts of film-forming additives are added, most commonly vinylene carbonate (VC) and fluoroethylene carbonate (FEC). These additives are consumed preferentially during the first charge to build a durable solid electrolyte interphase (SEI) on the anode, which improves cycle life and stability. The electrolyte is thus one of the most chemistry-intensive parts of the cell, drawing on DMC, DEC, EMC, the LiPF6 salt, and additives including VC and FEC.

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Stage 5: The separator

The separator is a thin microporous membrane placed between the anode and cathode to prevent electrical contact while allowing lithium ions to pass through its pores. It is typically made from a polyolefin such as polyethylene or polypropylene, and in many modern cells it carries a thin ceramic coating (often alumina) to improve thermal stability and safety. Although it contains no active material, the separator is critical to cell safety, which is one of LFP's core strengths.


Stage 6: Cell assembly

With electrodes and separator prepared, the cell is assembled. The coated foils are cut to size, and the cathode, separator, and anode are combined either by stacking flat layers or by winding them into a jelly roll, depending on the cell format. Metal tabs are welded to the uncoated edges of the foils to carry current out of the cell, aluminum for the cathode and typically nickel or copper for the anode. The electrode assembly is inserted into its housing, which for LFP in electric vehicles and energy storage is most often a prismatic can, though cylindrical and pouch formats are also used.

The cell is then filled with the liquid electrolyte under carefully controlled, moisture-free conditions, because LiPF6 reacts with water. After filling, the cell is sealed.


Stage 7: Formation, aging, and testing

A freshly assembled cell is not yet functional. It must go through formation, a sequence of precisely controlled first charge and discharge cycles. During this first charge, the electrolyte additives react at the anode surface to build the solid electrolyte interphase (SEI), the protective layer that governs the cell's long-term stability and cycle life. Formation is one of the most time-consuming and capital-intensive stages of cell manufacturing.

After formation, cells are often degassed (to remove gases generated during SEI formation), then aged for a period under monitored conditions. Finally, each cell's capacity, voltage, and internal resistance are measured and the cells are graded and sorted, so that cells with matched characteristics are grouped together into modules and packs. This quality control is essential for the performance and safety of the finished battery.


Why LFP, and where it is made

LFP's manufacturing has scaled rapidly because the chemistry fits the market. According to the International Energy Agency, LFP accounted for more than 55% of EV batteries deployed globally in 2025 and more than 90% of stationary energy storage installations, with LFP packs running more than 40% cheaper per kWh than nickel-based NMC. Its lower energy density matters less for grid storage and for entry and mid-tier vehicles, which is where its share is concentrated.

LFP cell production has historically been concentrated in China, and manufacturing of the cathode material and its precursors remains heavily concentrated there. US cell capacity is now expanding quickly, led by energy storage, but domestic production of the upstream cathode materials and chemical inputs has lagged the cell plants. For manufacturers building out US supply, that gap between domestic cell capacity and domestic materials supply is the central sourcing challenge, and the reason securing qualified, well-documented raw material supply matters as much as the cell manufacturing itself.


Frequently asked questions

What are LFP batteries made of?
An LFP battery is made of a lithium iron phosphate cathode on aluminum foil, a graphite anode on copper foil, a liquid electrolyte of lithium hexafluorophosphate (LiPF6) dissolved in organic carbonate solvents, and a microporous polymer separator.

How is the LFP cathode material made?
The common industrial route converts ferrous sulfate into battery-grade ferric phosphate, then blends that with lithium carbonate and a carbon source and calcines it at high temperature to form lithium iron phosphate (LiFePO4).

What chemicals are used in LFP battery manufacturing?
Key inputs include ferrous sulfate, ferric phosphate, and lithium carbonate for the cathode; graphite for the anode; NMP solvent and PVDF binder for the cathode electrode; CMC and SBR for the anode; and LiPF6 salt with EC, DMC, EMC, and DEC solvents plus VC and FEC additives for the electrolyte.

Why do LFP batteries use graphite anodes?
Graphite reversibly stores lithium ions during charging and offers a stable, low-cost, long-life anode. Some manufacturers add small amounts of silicon to increase energy density, but graphite remains the base material.

What is formation in battery manufacturing?
Formation is the first controlled charge and discharge of a newly assembled cell. It builds the solid electrolyte interphase (SEI) on the anode, a protective layer essential to the cell's cycle life and stability.

Why is LFP more popular than NMC for energy storage?
LFP is cheaper per kWh, contains no nickel or cobalt, and offers strong safety and long cycle life. Its lower energy density is a smaller drawback for stationary storage, where it now dominates.